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The Cryosphere An interactive open-access journal of the European Geosciences Union
The Cryosphere, 10, 1647-1663, 2016
https://doi.org/10.5194/tc-10-1647-2016
© Author(s) 2016. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
29 Jul 2016
Isotopic exchange on the diurnal scale between near-surface snow and lower atmospheric water vapor at Kohnen station, East Antarctica
François Ritter1,2, Hans Christian Steen-Larsen2,3, Martin Werner1, Valérie Masson-Delmotte2, Anais Orsi2, Melanie Behrens1, Gerit Birnbaum1, Johannes Freitag1, Camille Risi4, and Sepp Kipfstuhl1 1Alfred-Wegener-Institut (AWI) Helmholtz Zentrum für Polar und Meeresforschung, Bremerhaven, Germany
2Laboratoire des Sciences du Climat et de l'Environnement (LSCE), IPSL/CEA-CNRS-UVSQ, Saclay, Gif-sur-Yvette, France
3Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, Copenhagen, Denmark
4Laboratoire de Météorologie Dynamique (LMD), IPSL/CNRS-UPMC, Paris, France
Abstract. Quantifying the magnitude of post-depositional processes affecting the isotopic composition of surface snow is essential for a more accurate interpretation of ice core data. To achieve this, high temporal resolution measurements of both lower atmospheric water vapor and surface snow isotopic composition are required. This study presents continuous measurements of water vapor isotopes performed in East Antarctica (Kohnen station) from December 2013 to January 2014 using a laser spectrometer. Observations have been compared with the outputs of two atmospheric general circulation models (AGCMs) equipped with water vapor isotopes: ECHAM5-wiso and LMDZ5Aiso. During our monitoring period, the signals in the 2 m air temperature T, humidity mixing ratio q and both water vapor isotopes δD and δ18O are dominated by the presence of diurnal cycles. Both AGCMs simulate similar diurnal cycles with a mean amplitude 30 to 70 % lower than observed, possibly due to an incorrect simulation of the surface energy balance and the boundary layer dynamics. In parallel, snow surface samples were collected each hour over 35 h, with a sampling depth of 2–5 mm. A diurnal cycle in the isotopic composition of the snow surface is observed in phase with the water vapor, reaching a peak-to-peak amplitude of 3 ‰ for δD over 24 h (compared to 36 ‰ for δD in the water vapor). A simple box model treated as a closed system has been developed to study the exchange of water molecules between an air and a snow reservoir. In the vapor, the box model simulations show too much isotopic depletion compared to the observations. Mixing with other sources (advection, free troposphere) has to be included in order to fit the observations. At the snow surface, the simulated isotopic values are close to the observations with a snow reservoir of  ∼ 5 mm depth (range of the snow sample depth). Our analysis suggests that fractionation occurs during sublimation and that vapor–snow exchanges can no longer be considered insignificant for the isotopic composition of near-surface snow in polar regions.

Citation: Ritter, F., Steen-Larsen, H. C., Werner, M., Masson-Delmotte, V., Orsi, A., Behrens, M., Birnbaum, G., Freitag, J., Risi, C., and Kipfstuhl, S.: Isotopic exchange on the diurnal scale between near-surface snow and lower atmospheric water vapor at Kohnen station, East Antarctica, The Cryosphere, 10, 1647-1663, https://doi.org/10.5194/tc-10-1647-2016, 2016.
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We present successful continuous measurements of water vapor isotopes performed in Antarctica in January 2013. The interest is to understand the impact of the water vapor isotopic composition on the near-surface snow isotopes. Our study reveals a diurnal cycle in the snow isotopic composition in phase with the vapor. This finding suggests fractionation during the sublimation of the ice, which has an important consequence on the interpretation of water isotope variations in ice cores.
We present successful continuous measurements of water vapor isotopes performed in Antarctica in...
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